研究方向 ：主族元素化学，配位化学，计算化学
电话 ：+86 18708420237
E-Mail：dongzhaowen@scu.edu.cn
一、学习及工作经历
2022.07–至今 四川大学化学学院，特聘研究员，博士生导师
2019.04–2022.05 瑞士洛桑联邦理工学院（EPFL），博士后，合作导师：Kay Severin 教授
2019.01–2019.03德国奥登堡大学，博士后，合作导师：Thomas Müller 教授
2015.07–2018.12 德国奥登堡大学，博士（Summa Cum Laude拉丁文最高荣誉学位），导师：Thomas Müller教授
2012.09–2015.06 杭州师范大学有机硅化学及材料教育部重点实验室，硕士，导师：李志芳教授
二、主要研究方向
低价（低配位）主族元素化合物由于其特殊的电子结构和性质，在小分子活化、催化以及能源材料等领域展现出重要的应用前景。如何高效合成结构新颖且具有高反应活性的低价（低配位）主族元素化合物一直是当代主族元素化学的研究热点和前沿。
目前主要研究方向包括：1. 新型低配位p区化合物的合成及其反应性研究; 2. 新型主族元素掺杂的“芳香性”杂环配体的合成及其在金属配位化学中的应用; 3. 新型硼燃料的开发和利用。
三、主要工作业绩
董召文博士近年来一直致力于主族元素化学研究，围绕含硅、锗元素的高反应活性中间体的“高效合成”、“新结构”和“新性质”等科学问题，开展了系统研究。主要贡献包括三个方面：1）开发了一种合成“高反应活性”硅、锗化合物的新方法；2）构建了几种结构新颖的重十四族元素的卡宾类似物，并系统探究了它们在小分子活化领域的应用；3）首次通过实验验证了路易斯酸碱反应的单电子转移机理。目前已在国际著名刊物共计发表SCI论文26篇，其中第一作者论文17篇，包括1篇Acc. Chem. Res.、3篇J. Am. Chem. Soc.、3篇Angew. Chem. Int. Ed.、2篇Chem. Sci.以及4篇 Chem. Eur. J.；其中5篇文章被选为封面文章。
四、主要奖励和荣誉
2022年 四川省“天府峨眉计划”青年人才项目
2021年 四川大学“双百人才工程”B计划
2018年 德国奥登堡大学优秀博士论文奖
2017年 国家优秀自费留学生奖学金
2015年 德国“Georg-Lichtenberg-Promotionsstipendien”博士奖学金
五、代表性成果 （获奖成果、专著、论文、专利）
1. Paul Varava; Zhaowen Dong, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Kay Severin*, Isolation and Characterization of Diazoolefins, Nat. Chem. 2021, 13, 1055−1060. (highlighted in Nat. Chem. 2021, 13, 1030–1032)
2. Zhaowen Dong, Jan Mathis Winkler, Marc Schmidtmann, Thomas Müller*, Three-membered Cyclic Digermylenes Stabilized by an N-heterocyclic Carbene, Chem. Sci. 2021, 12, 6287−6292. (featured on the inside cover; selected as 2021 Chemical Science HOT article; highlighted in ChemistryViews)
3. Zhaowen Dong, Lena Albers, Thomas Müller*, Trialkylsilyl-Substituted Silole and Germole D ianions as Precursors for Unusual Silicon and Germanium Compounds, Acc. Chem. Res. 2020, 53, 532−543.
4. Zhaowen Dong, Cristian Pezzato, Andrzej Sienkiewicz, Rosario Scopelliti, Farzaneh Fadaei Tirani, Kay Severin*, SET Processes in Lewis Acid–Base Reactions: The Tritylation of N-Heterocyclic Carbenes, Chem. Sci. 2020, 11, 7615−7618.
5. Zhaowen Dong, Katja Bedbur, Marc Schmidtmann, Thomas Müller*, Hafnocene-based Bicyclo[2.1.1]hexene Germylenes–Formation, Reactivity, and Structural Flexibility, J. Am. Chem. Soc., 2018, 140, 3052−3060.
6. Zhaowen Dong, Hanna H. Cramer, Marc Schmidtmann, Lucas A. Paul, Inke Siewert, Thomas Müller*, Evidence for Single Electron Shift in a Lewis Acid Base Reaction, J. Am. Chem. Soc. 2018, 140, 15419−15424. (featured on the supplementary cover; highlighted in Nachr. Chem.)
7. Zhaowen Dong, Oliver Janka, Jutta Koesters, Marc Schmidtmann, Thomas Müller*, A Dimeric η1, η5-Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti-Ge-Ge-Ti Bond, Angew. Chem. Int. Ed. 2018, 57, 8634−8638.
8. Patrik. Tholen, Zhaowen Dong, Marc Schmidtmann, Lena Albers, Thomas. Müller*, A Neutral η5-Aminoborole Complex of Germanium(II), Angew. Chem. Int. Ed. 2018, 57, 13319–13324.
9. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, A Stable Silylene with a σ2, π-Butadiene Ligand, J. Am. Chem. Soc. 2017, 139, 7117−7123.
10. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, A Germylene Stabilized by Homoconjugation, Angew. Chem. Int. Ed. 2016, 55, 15899−15904.
11. Xu-Qiong Xiao#, Zhaowen Dong# (co-first author), Zhifang Li*, Chenting Yan, Guoqiao Lai, Mitsuo Kira*, 1,3-D iazasilabicyclo[1.1.0]butane with a Long Bridging N-N Bond, Angew. Chem. Int. Ed. 2016, 55, 3758−3762.
12. Zhaowen Dong*, Andrzej Sienkiewicz, Abdusalom A. Suleymanov, Cesare Berton, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Kay Severin*, A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion, Chem. Eur. J. 2022, 28, e20220089.
13. Zhaowen Dong, J. Terence Blaskovits, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Andrzej Sienkiewicz, Clémence Corminboeuf*, Kay Severin*, Tuning the π-Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study, Chem. Eur. J. 2021, 27, 11983-11988.
14. Zhaowen Dong, Marc Schmidtmann, Thomas Müller*, Potassium Salts of 2,5‐Bis(trimethylsily l)‐Germolide: Switching between Aromatic and Non‐Aromatic States, Chem. Eur. J. 2019, 25, 10858−10865. (selected as hot paper and featured on the front cover)
15. Zhaowen Dong, Lena Albers, Marc Schmidtmann, Thomas Müller*, A Germacalicene: Synthesis, Structure, and Reactivity, Chem. Eur. J. 2019, 25, 1098−1105. (selected as hot paper)
16. Zhaowen Dong, Crispin R. W. Reinhold, Marc Schmidtmann, Thomas Müller*, Trialkylsilyl-Substituted Silole and Germole Dianions, Organometallics 2018, 37, 4736−4743.
17. Zhaowen Dong, Zhifang Li*, Xupeng Liu, Chenting Yan, Ningka Wei, Mitsuo Kira*, Thomas Müller*, Dihydrogen Splitting Using Dialkylsilylene-Based Frustrated Lewis Pairs, Chem. Asian J. 2017, 12, 1204−1207 (special issue on advances in silicon chemistry and featured on the back cover).
18. Zhaowen Dong, Marc Schmidtmann, Thomas Müller*, Reactivity of a Bicyclo[2.1.1]hexene Germylene towards Elemental Chalcogens, Z. Anorg. Allg. Chem. 2018, 644, 1041–1046.
19. Zhaowen Dong, Xuqiong Xiao, Zhifang Li*, Qiong Lu, Guoqiao Lai, Mitsuo Kira*, Elusive 2H-1,2-Oxasiletes Through Reactions of an Isolable Dialkylsilylene with Diazocarbonyl Compounds, Org. Biomol. Chem. 2015, 13, 9471−9476.
20. Bastiaan Kooij, Zhaowen Dong, Paul Varava, Farzaneh Fadaei-Tirani, Rosario Scopelliti, Laura Piveteau and Kay Severin*, Vanadium Complexes with N-Heterocyclic Vinylidene Ligands, Chem. Commun., 2022, 58, 4204–4207.
21. Hong Zhang, Felix Thomas Eickemeyer, ……. Zhaowen Dong, Jovana V. Milić*, Michael Grätzel*, Multimodal Host–Guest Complexation for Efficient and Stable Perovskite Photovoltaics, Nat. Commun. 2021, 12, 3383–3393.
22. Shaofeng Pang,* Fangfang Liu, Yujing Zhang, Zhaowen Dong, Qiong Su, Wenfang Wang, Zhenhua Li, Feng Zhou, and Yanbin Wang*, Construction of Functional Superhydrophobic Biochars as Hydrogen Transfer Catalysts for Dehydrogenation of N-Heterocycles, ACS Sustainable Chem. Eng. 2021, 9, 9062–9077.
23. Abdusalom A. Suleymanov, Eliott Le Du, Zhaowen Dong, Bastian Muriel, Rosario Scopelliti, Farzaneh Fadaei-Tirani, Jeróme Waser,* and Kay Severin*, Triazene-Activated Donor–Acceptor Cyclopropanes: Ring-Opening and (3+2) Annulation Reactions, Org. Lett. 2020, 11, 4517−4522.
24. Crispin R. W. Reinhold, Zhaowen Dong, Jan M. Winkler, Henning Steinert, Marc Schmidtmann, and Thomas Meller*, A One-Step Germole to Silole Transformation and a Stable Isomer of a Disilabenzene, Chem. Eur. J. 2018, 24, 848−854.
25. Xupeng Liu, Xuqiong Xiao, Zheng Xu, Xiuming Yang, Zhifang Li*, Zhaowen Dong, Chengting Yan, Guoqiao Lai, Mitsuo Kira*, Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes, Organometallics 2014, 33, 5434−5439.